mer and fac isomerism in tris chelate diimine metal complexes

Author:

Dabb Serin L.12345,Fletcher Nicholas C.12345

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Queen's University of Belfast

3. David Keir Building

4. Belfast

5. UK

Abstract

This overview analyzes the delicate interplay of the factors that control mer and fac isomerism in diimine tris-chelate complexes, giving consideration to the distribution of products in labile systems, the methods to isolate inert complexes and the implications to self-assembled coordination cages.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference137 articles.

1. Comprehensive Coordination Chemistry II: From Biology to Nanotechnology, ed. J. A. McCleverty and M. T. J., Elsevier Pergammon, Oxford, 2nd edn, 2004

2. H. Amouri and M.Gruselle, Chirality in Transition Metal Chemistry: Molecules, Supramolecular Assemblies and Materials, Wiley-Blackwell, Chichester, 2008

3. A. von Zelewsky , Stereochemistry of Coordination Compounds, Wiley, Chichester, U.K., 1996

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