Surface engineering of earth-abundant Fe catalysts for selective hydrodeoxygenation of phenolics in liquid phase-Reference-Cited by-同舟云学术

Surface engineering of earth-abundant Fe catalysts for selective hydrodeoxygenation of phenolics in liquid phase

Published:2020 Issue:23 Volume:11 Page:5874-5880
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Jianghao¹²³⁴^ORCID,Sun Junming¹²³⁴^ORCID,Kovarik Libor⁵⁶⁷⁸⁴,Engelhard Mark H.⁵⁶⁷⁸⁴^ORCID,Du Lei⁹¹⁰¹¹¹²,Sudduth Berlin¹²³⁴,Li Houqian¹²³⁴,Wang Yong¹²³⁴⁵

Affiliation:

1. The Gene & Linda Voiland School of Chemical Engineering and Bioengineering

2. Washington State University

3. Pullman

4. USA

5. Institute for Integrated Catalysis

6. Environmental Molecular Sciences Laboratory

7. Pacific Northwest National Laboratory

8. Richland

9. School of Chemistry and Chemical Engineering

10. Harbin Institute of Technology

11. Harbin 150001

12. China

Abstract

Tailoring the graphene-covered Fe with Cs modifies the surface electronic properties of the catalysts such that selective C–O bond cleavage of phenol is achieved in liquid phase by inhibiting the facile tautomerization followed by ring saturation.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00983K

Reference54 articles.

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2. Catalysis with two-dimensional materials and their heterostructures

3. Enhanced Electron Penetration through an Ultrathin Graphene Layer for Highly Efficient Catalysis of the Hydrogen Evolution Reaction