Positive shift in corrole redox potentials leveraged by modest β-CF3-substitution helps achieve efficient photocatalytic C–H bond functionalization by group 13 complexes-Reference-Cited by-同舟云学术

Positive shift in corrole redox potentials leveraged by modest β-CF3-substitution helps achieve efficient photocatalytic C–H bond functionalization by group 13 complexes

Published:2019 Issue:32 Volume:48 Page:12279-12286
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhan Xuan¹²³⁴^ORCID,Yadav Pinky¹²³⁴,Diskin-Posner Yael⁵⁶⁷⁴^ORCID,Fridman Natalia¹²³⁴,Sundararajan Mahesh⁸⁹¹⁰¹¹¹²,Ullah Zakir⁸⁹¹⁰¹¹¹²,Chen Qiu-Cheng¹²³⁴,Shimon Linda J. W.⁵⁶⁷⁴^ORCID,Mahammed Atif¹²³⁴,Churchill David G.¹²³⁴⁸^ORCID,Baik Mu-Hyun⁸⁹¹⁰¹¹¹²^ORCID,Gross Zeev¹²³⁴^ORCID

Affiliation:

1. Schulich Faculty of Chemistry

2. Technion-Israel Institute of Technology

3. Haifa 32000

4. Israel

5. Department of Chemical Research Support

6. Weizmann Institute of Science

7. Rehovot 76100

8. Department of Chemistry

9. Korea Advanced Institute of Science and Technology (KAIST)

10. Daejeon

11. Republic of Korea

12. Center for Catalytic Hydrocarbon Functionalizations

Abstract

Tris- and tetrakis-β-trifluoromethylated gallium (3CF3-Ga, 4CF3-Ga) and aluminum (3CF3-Al, 4CF3-Al) corrole systems were synthesized by a facile “one-pot” approach and studied in the context of photocatalytic C–H bond activation.

Funder

Israel Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02150G

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