Electrochemical valorization of HCl for the production of chlorine via a proton-filter functional covalent organic framework

Author:

Kaur Sukhjot1,Ranjeesh Kayaramkodath C.2,Garg Kalpana1,Gaber Safa2,Mehta Shivangi1,Nagaiah Tharamani C.1ORCID,Shetty Dinesh23ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001, India

2. Department of Chemistry, Khalifa University of Science & Technology, P.O. Box 127788, Abu Dhabi, UAE

3. Center for Catalysis and Separations (CeCaS), Khalifa University of Science & Technology, P.O. Box 127788, Abu Dhabi, UAE

Abstract

An in situ proton filter covalent organic framework (COF) is developed to integrate the chlorine evolution reaction (CER) with the oxygen-depolarized cathode and an excellent CER faradaic efficiency of 92% is achieved.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research

Khalifa University of Science, Technology and Research

Publisher

Royal Society of Chemistry (RSC)

Reference53 articles.

1. Low-Voltage Gaseous HCl Electrolysis with an Iron Redox-Mediated Cathode for Chlorine Regeneration

2. HCl Oxidation on IrO2-Based Catalysts: From Fundamentals to Scale-Up

3. R.Stringer and P.Johnston , 2001

4. Chlorination for low-cost household water disinfection – A critical review and status in three Latin American countries

5. Centers for Disease Control and Prevention , 2020 , https://www.cdc.gov/healthywater/drinking/public/water_disinfection.html?CDC_AA_refVal=https%3A%2F%2Fwww.cdc.gov%2Fhealthywater%2Fdrinking%2Fpublic%2Fchlorine-disinfection.html#print

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