Discovery of anion–π interactions in the recognition mechanism of inorganic anions by 1,2,3-triazolium rings

Author:

Caballero Antonio123,Zapata Fabiola123,González Lidia123,Molina Pedro123,Alkorta Ibon456,Elguero José456

Affiliation:

1. Departamento de Química Orgánica

2. Universidad de Murcia

3. Murcia, Spain

4. Instituto de Química Médica

5. CSIC

6. E-28006 Madrid, Spain

Abstract

The simultaneous action of two noncovalent interactions in solution, hydrogen-bonding and anion–π, resulted in a selective receptor for HP2O73− anions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference38 articles.

1. Supramolecular Chemistry of Anions , ed. A. Bianchi , K. Bowman-James and E. García-España , Wiley-VCH , New York , 1997

2. J. L. Sessler , P. A.Gale and W.-S.Cho , Anion Receptor Chemistry , RSC Publishing, The Royal Society of Chemistry , Cambridge , 2006

3. Design, Synthesis, and Self-Assembling Properties of Novel Triazolophanes

4. Heterocyclic Peptide Backbone Modifications in an α-Helical Coiled Coil

5. Pure CH Hydrogen Bonding to Chloride Ions: A Preorganized and Rigid Macrocyclic Receptor

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