Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions

Author:

González-Izquierdo Palmerina12ORCID,de Pedro Imanol1,Cañadillas-Delgado Laura2,Beobide Garikoitz34,Vallcorba Oriol5ORCID,Sánchez-Andújar Manuel6ORCID,Fernández-Díaz María Teresa2,Fernández Jesús Rodríguez1ORCID,Fabelo Oscar2ORCID

Affiliation:

1. CITIMAC, Facultad de Ciencias, Universidad de Cantabria, 39005 Santander, Spain

2. Institut Laue-Langevin, BP 156X, F-38042 Grenoble Cedex, France

3. Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apartado 644, E-48080, Bilbao, Spain

4. Basque Ctr Mat Applicat & Nanostruct, BCMat, UPV EHU Sci Pk, Leioa 48940, Spain

5. ALBA Synchrotron Light Source, Cerdanyola del Vallés, Barcelona, Spain

6. QuiMolMat Group, Department of Chemistry, Faculty of Science and Advanced Scientific Research Center (CICA), University of A Coruna, Zapateira, 15071 A Coruna, Spain

Abstract

The ketonization of the quinuclidine molecule were used to synthesize and physically characterize two paramagnetic hybrid compounds. The significant increase in the conductivity at HT is related with a crystal to plastic crystal phase transition.

Funder

Universidad de Cantabria

Euskal Herriko Unibertsitatea

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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