Rational design of a room temperature molecular spin switch. The light-driven coordination induced spin state switch (LD-CISSS) approach

Author:

Dommaschk M.123,Schütt C.123,Venkataramani S.45,Jana U.678,Näther C.9210,Sönnichsen F. D.123,Herges R.123

Affiliation:

1. Otto-Diels-Institut für Organische Chemie

2. Christian-Albrechts-Universität

3. D-24098 Kiel, Germany

4. Indian Institute for Science Education and Research (IISER) Mohali

5. Manauli PO 140306, India

6. Department of Chemistry

7. Jadavpur University

8. Kolkata-700032, India

9. Institut für Anorganische Chemie

10. 24098 Kiel, Germany

Abstract

A record player type molecule changes spin state reversibly upon irradiation with green and blue light in solution at room temperature without measureable fatigue.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference49 articles.

1. M. P. Shores , C. M.Klug and S. R.Fiedler , Spin-Crossover Materials: Properties and Applications , ed. M. A. Halcrow , John Wiley & Sons, Ltd. , 1st edn, 2013 , ch. 10, pp. 281–301

2. A magnetic iron(iii) switch with controlled and adjustable thermal response for solution processing

3. Inducing hysteretic spin crossover in solution

4. M. P. Shores , C. M.Klug and S. R.Fiedler , Spin-Crossover Materials , ed. M. A. Halcrow , 2013 , pp. 281–301

5. Spin Transition Molecular Materials: Intelligent Contrast Agents for Magnetic Resonance Imaging

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