A neutral crystalline imino-substituted silyl radical-Reference-Cited by-同舟云学术

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A neutral crystalline imino-substituted silyl radical

Published:2024 Issue:65 Volume:60 Page:8577-8580
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kiefer Fiona J.¹,Kostenko Arseni¹^ORCID,Holzner Richard¹^ORCID,Inoue Shigeyoshi¹^ORCID

Affiliation:

1. TUM School of Natural Sciences, Department of Chemistry, Wacker-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85748 Garching bei München, Germany

Abstract

The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of ItBuN-SiBr3 with NaSitBu2Me. The radical was fully characterized by SC-XRD and EPR spectroscopy and supported by quantum chemical calculations.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02167C

Reference35 articles.

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4. Z.Rappoport and Y.Apeloig , The chemistry of organic silicon compounds , Wiley , New York , 2001

5. C.Chatgilialoglu , Organosilanes in radical chemistry , John Wiley and Sons, Ltd , Chichester, Hoboken, NJ , 2004

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