An isoindoline bridged [M(η6-arene)2]+ (M = Re, 99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality-Reference-Cited by-同舟云学术

An isoindoline bridged [M(η⁶-arene)₂]⁺ (M = Re, ^99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality

Published:2022 Issue:25 Volume:51 Page:9591-9595
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Csucker Joshua¹^ORCID,Jo Da Kyung¹,Nadeem Qaisar¹,Blacque Olivier¹^ORCID,Fox Thomas¹,Braband Henrik¹^ORCID,Alberto Roger¹^ORCID

Affiliation:

1. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland

Abstract

We report the synthesis of novel rhenium and 99mTc ansa-arenophane complexes with bridging isoindolines. Inter-instead of intramolecular isoindoline formation leads to dinuclear macrocycles, one of which exhibits axial chirality.

Funder

Universität Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00743F

Reference27 articles.

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4. Tin-Bridged ansa-Metallocenes of the Late Transition Metals Cobalt and Nickel: Preparation, Molecular and Electronic Structures, and Redox Chemistry

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