Ce(OH)2Cl and lanthanide-substituted variants as precursors to redox-active CeO2 materials-Reference-Cited by-同舟云学术

Ce(OH)2Cl and lanthanide-substituted variants as precursors to redox-active CeO2 materials

Published:2020 Issue:42 Volume:49 Page:14871-14880
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dunn Alexander J. A.¹²³⁴,Annis James W.¹²³⁴,Fisher Janet M.⁵⁶⁴,Thompsett David⁵⁶⁴,Walton Richard I.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Warwick

3. Coventry

4. UK

5. Johnson Matthey Technology Centre

6. Reading

Abstract

Lanthanide hydroxide-chlorides Ce_1−xLn_x(OH)₂Cl for Ln = La, Pr, Gd, Tb crystallise from poly(ethylene) glycol (M_n = 400) at 240 °C. Subsequent thermal decomposition yields oxides Ce_1−xLn_xO_2−δ with redox properties suited for heterogeneous catalysis.

Funder

Office of the Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03435E

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