Comparing interfacial cation hydration at catalytic active sites and spectator sites on gold electrodes: understanding structure sensitive CO<sub>2</sub> reduction kinetics-Reference-Cited by-同舟云学术

Comparing interfacial cation hydration at catalytic active sites and spectator sites on gold electrodes: understanding structure sensitive CO₂ reduction kinetics

Published:2022 Issue:25 Volume:13 Page:7634-7643
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rebstock Jaclyn A.¹^ORCID,Zhu Quansong¹,Baker L. Robert¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, USA

Abstract

Site-specific vibrational probes were used to elucidate the interfacial solvation structure between catalytic active sites and inactive sites on a Au electrode to reveal a unique, opposing cation-dependent double layer structure at active sites.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01878K

Reference66 articles.

1. Opportunities and challenges for a sustainable energy future

2. Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction

3. Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes