Copper-catalyzed olefinic C–H difluoroacetylation of enamides-Reference-Cited by-同舟云学术

Copper-catalyzed olefinic C–H difluoroacetylation of enamides

Published:2014 Issue:44 Volume:50 Page:5887-5890
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Caillot Gilles¹²³⁴,Dufour Jérémy¹²³⁴,Belhomme Marie-Charlotte⁵⁶⁷⁸⁹,Poisson Thomas⁵⁶⁷⁸⁹,Grimaud Laurence¹⁰¹¹¹²¹³¹⁴,Pannecoucke Xavier⁵⁶⁷⁸⁹,Gillaizeau Isabelle¹²³⁴

Affiliation:

1. Institut de Chimie Organique et Analytique

2. UMR 7311 CNRS

3. Université d'Orléans

4. 45067 Orléans cedex 2, France

5. Normandie Univ

6. COBRA

7. UMR 6014 and FR 3038

8. Univ Rouen

9. INSA Rouen

10. Ecole Normale Supérieure-PSL Research University

11. Département de Chimie

12. Sorbonne Universités - UPMC Univ Paris 06

13. CNRS UMR 8640 PASTEUR

14. 75005 Paris, France

Abstract

An efficient copper-catalyzed method for the regioselective synthesis of β-difluoroester substituted enamides using BrCF₂CO₂Et is reported for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC01994F

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5. On the polarity of partially fluorinated methyl groups

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