Efficient electrocatalytic CO2 reduction with a molecular cofacial iron porphyrin dimer-Reference-Cited by-同舟云学术

Efficient electrocatalytic CO2 reduction with a molecular cofacial iron porphyrin dimer

Published:2015 Issue:95 Volume:51 Page:16900-16903
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mohamed Eman A.¹²³⁴⁵,Zahran Zaki N.¹²³⁴⁵,Naruta Yoshinori¹²³⁴⁵

Affiliation:

1. Center for Chemical Energy Conversion Research

2. Institute for Science and Technology Research

3. Chubu University

4. Kasugai 487-8501

5. Japan

Abstract

A cofacial iron porphyrin dimer, o-Fe2DTPP, efficiently and selectively catalyzes the electrochemical reduction of CO₂ to CO in DMF/10% H₂O solution with 4300 s⁻¹ TOF.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04273A

Reference39 articles.

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2. Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts

3. Multi-electron reduction of CO2 via RuCO2, C(O)OH, CO, CHO, and CH2OH species

4. Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO)3Cl (bipy = 2,2′-bipyridine)

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