Core structure dependence of cycloreversion dynamics in diarylethene analogs
Author:
Affiliation:
1. Department of Chemistry
2. Johns Hopkins University
3. Baltimore
4. USA
Abstract
Increased core rigidity in diarylethene-type photoswitches results in shallower excited-state potential energy surfaces and faster funneling towards the conical intersections from which cycloreversion and nonreactive deactivation occur.
Funder
Division of Chemistry
Johns Hopkins University
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP05797H
Reference59 articles.
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4. S. Chen , W.Li and W.-H.Zhu , Novel Ethene-Bridged Diarylethene Photochromic Systems: Self-Assembly, Photoswitches, and Molecular Logic Gates , in Photon-Working Switches , ed. Y. Yokoyama and K. Nakatani , Springer , Japan , 2017 , pp. 37–68
5. Photochemical Reversibility of Ring-Closing and Ring-Opening Reactions in Diarylperfluorocyclopentenes
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