Core structure dependence of cycloreversion dynamics in diarylethene analogs

Author:

Honick Chana R.1234,Peters Garvin M.1234ORCID,Young Jamie D.1234,Tovar John D.1234ORCID,Bragg Arthur E.1234ORCID

Affiliation:

1. Department of Chemistry

2. Johns Hopkins University

3. Baltimore

4. USA

Abstract

Increased core rigidity in diarylethene-type photoswitches results in shallower excited-state potential energy surfaces and faster funneling towards the conical intersections from which cycloreversion and nonreactive deactivation occur.

Funder

Division of Chemistry

Johns Hopkins University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference59 articles.

1. Photochromism of Diarylethene Molecules and Crystals: Memories, Switches, and Actuators

2. Diarylethenes for Memories and Switches

3. Synthesis and Photochromic Properties of Functional Diarylethene with a 2,5-Dihydrothiophene Bridging Unit

4. S. Chen , W.Li and W.-H.Zhu , Novel Ethene-Bridged Diarylethene Photochromic Systems: Self-Assembly, Photoswitches, and Molecular Logic Gates , in Photon-Working Switches , ed. Y. Yokoyama and K. Nakatani , Springer , Japan , 2017 , pp. 37–68

5. Photochemical Reversibility of Ring-Closing and Ring-Opening Reactions in Diarylperfluorocyclopentenes

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3