Triple 1D1D superatomic bonding. Au22(dppo)6 as a Π4- and Δ2-triply bonded cluster based on Au11 assembled units-Reference-Cited by-同舟云学术

Triple 1D1D superatomic bonding. Au22(dppo)6 as a Π4- and Δ2-triply bonded cluster based on Au11 assembled units

Published:2020 Issue:3 Volume:22 Page:1422-1426
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Muñoz-Castro Alvaro¹²³⁴⁵^ORCID

Affiliation:

1. Grupo de Química Inorgánica y Materiales Moleculares

2. Facultad de Ingenieria

3. Universidad Autonoma de Chile

4. Santiago

5. Chile

Abstract

Our analysis reveals the Au₂₂(dppo)₆ cluster as a triple-bonded 22-valence electron (ve) supermolecule, featuring a bonding scheme based on 1D + 1D shell combinations, which largely contrasts with the developed bonding of [Au₁₃]⁵⁺ core derivatives.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP05790K

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