Synthesis of a new poly([R]-3-hydroxybutyrate) RAFT agent-Reference-Cited by-同舟云学术

Synthesis of a new poly([R]-3-hydroxybutyrate) RAFT agent

Published:2016 Issue:9 Volume:7 Page:1693-1700
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Jiang Lu¹²³⁴⁵,Liow Sing Shy¹²³⁴⁵,Loh Xian Jun¹²³⁴⁵

Affiliation:

1. Institute of Materials Research and Engineering

2. A*STAR (Agency for Science

3. Technology and Research)

4. Innovis

5. Republic of Singapore

Abstract

Biodegradable, sustainable and biocompatible natural poly([R]-3-hydroxybutyrate) (PHB) has been modified by 1-hexanol through transesterification to form a mono-hydroxylated PHB, which reacted with thiocarbonylthio compound to generate macro mono-hydroxylated PHB chain transfer agent (CTA) for RAFT polymerization with DMAEMA monomer. Kinetic processes of transesterification reaction and RAFT polymerization were carefully investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C5PY01812A

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