Dramatic enhancement of spin–spin coupling and quenching of magnetic dimensionality in compressed silver difluoride

Author:

Kurzydłowski Dominik12345ORCID,Derzsi Mariana12346ORCID,Barone Paolo78910,Grzelak Adam123411,Struzhkin Viktor12131415,Lorenzana José1617181910ORCID,Grochala Wojciech1234ORCID

Affiliation:

1. Center of New Technologies

2. University of Warsaw

3. 02-097 Warsaw

4. Poland

5. Faculty of Mathematics and Natural Sciences

6. Advanced Technologies Research Institute

7. SPIN-CNR

8. via Vetoio

9. 67100 L’Aquila

10. Italy

11. Faculty of Chemistry

12. Geophysical Laboratory

13. Carnegie Institution of Washington

14. Washington

15. USA

16. ISC-CNR

17. Dipartimento di Fisica

18. Università di Roma “La Sapienza”

19. 00185 Roma

Abstract

The high-pressure HP2 form of AgF2 features Ag2F73− units that are theoretically predicted to host extremely strong antiferromagnetic interactions, surpassing those seen in copper(ii) oxides.

Funder

Narodowe Centrum Nauki

Uniwersytet Warszawski

Ministero degli Affari Esteri e della Cooperazione Internazionale

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference34 articles.

1. Local and cooperative Jahn-Teller interactions in model structures

2. Crystal and magnetic structure of silver difluoride-II. Weak 4d-ferromagnetism of AgF2

3. Prediction of giant antiferromagnetic coupling in exotic fluorides of AgII

4. On the Covalency of Silver-Fluorine Bonds in Compounds of Silver(I), Silver(II) and Silver(III)

5. J. Gawraczyński , D.Kurzydłowski , W.Gadomski , Z.Mazej , G.Ruani , I.Bergenti , T.Jaroń , A.Ozarowski , S.Hill , P. J.Leszczyński , K.Tokár , M.Derzsi , P.Barone , K.Wohlfeld , J.Lorenzana and W.Grochala , arXiv:1804.00329

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