Effect of the nature of the nucleophile and solvent on an SNAr reaction-Reference-Cited by-同舟云学术

Effect of the nature of the nucleophile and solvent on an SNAr reaction

Published:2018 Issue:1 Volume:42 Page:260-264
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Gazitúa Marcela¹²³⁴⁵^ORCID,Tapia Ricardo A.⁶⁷⁴⁵,Contreras Renato⁸⁹⁴⁵,Campodónico Paola R.¹²³⁴⁵

Affiliation:

1. Centro de Química Médica

2. Facultad de Medicina

3. Clínica Alemana Universidad del Desarrollo

4. Santiago

5. Chile

6. Facultad de Química

7. Pontificia Universidad Católica de Chile

8. Departamento de Química, Facultad de Ciencias

9. Universidad de Chile

Abstract

The reaction of 2,4-dinitrobenzenesulfonyl chloride toward propylamine was kinetically evaluated in 19 organic solvents and 10 ionic liquids as reaction media.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ03212A

Reference31 articles.

1. F. Terrier , Nucleophilic Aromatic Displacement , New York , 1991

2. Effects ofortho- andpara-Ring Activation on the Kinetics of SNAr Reactions of 1-Chloro-2-nitro- and 1-Phenoxy-2-nitrobenzenes with Aliphatic Amines in Acetonitrile

3. Choice of Solvent (MeCN vs H2O) Decides Rate-Limiting Step in SNAr Aminolysis of 1-Fluoro-2,4-dinitrobenzene with Secondary Amines: Importance of Brønsted-Type Analysis in Acetonitrile

4. Aromatic Nucleophilic Substitution Reactions.

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