Origins of the odd optical observables in plutonium and americium tungstates-Reference-Cited by-同舟云学术

Origins of the odd optical observables in plutonium and americium tungstates

Published:2019 Issue:26 Volume:10 Page:6508-6518
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cross Justin N.¹²³⁴,Lee Tsung-Han⁵⁶⁷⁸,Kang Chang-Jong⁵⁶⁷⁸^ORCID,Yao Yong-Xin⁹¹⁰¹¹¹²⁸,Cary Samantha K.¹²³⁴,Stritzinger Jared T.¹²³⁴,Polinski Matthew J.¹³¹⁴¹⁵⁸,McKinley Carla D.¹³¹⁶¹⁷⁸^ORCID,Albrecht Schmitt Thomas E.¹³¹⁶¹⁷⁸^ORCID,Lanata Nicola⁵¹⁸¹⁹²⁰^ORCID

Affiliation:

1. Chemistry Division and the Plutonium Science and Manufacturing Directorate

2. Los Alamos National Laboratory

3. Los Alamos

4. 87545 USA

5. Department of Physics and Astronomy

6. Rutgers University

7. Piscataway

8. USA

9. Department of Physics and Astronomy and Ames Laboratory

10. U.S. Department of Energy

11. Iowa State University

12. Ames

13. Department of Chemistry and Biochemistry

14. Bloomsburg University of Pennsylvania

15. Bloomsburg

16. Florida State University

17. Tallahassee

18. Aarhus University

19. Aarhus C

20. Denmark

Abstract

A series of f-block tungstates show atypical coloration for both the Ce(iii) and Pu(iii) compounds; whereas the other lanthanide and Am(iii) compounds possess normal absorption features. The different optical properties are actually derived from the tungstate component rather than from 5f electrons/orbitals.

Funder

Basic Energy Sciences

Villum Fonden

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01174A

Reference79 articles.

1. Covalency in f-element bonds

2. N. A. Edelstein , J.Fuger , J. J.Katz and L. R.Morss , in The Chemistry of the Actinides and Transactinide Elements , ed. L. R. Morss , N. A. Edelstein , J. Fuger and J. J. Katz , Springer , Berlin , 4th edn, 2011 , vol. 3 , pp. 1753–1835

3. New evidence for 5f covalency in actinocenes determined from carbon K-edge XAS and electronic structure theory

4. Homoleptic Cerium(III) and Cerium(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State

5. Covalency in f-element complexes

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