Metamagnetic transition and a loss of magnetic hysteresis caused by electron trapping in monolayers of single-molecule magnet Tb2@C79N

Author:

Koutsouflakis Emmanouil1,Krylov Denis1,Bachellier Nicolas2,Sostina Daria2,Dubrovin Vasilii1ORCID,Liu Fupin1ORCID,Spree Lukas1ORCID,Velkos Georgios1ORCID,Schimmel Sebastian1,Wang Yaofeng1,Büchner Bernd1,Westerström Rasmus34ORCID,Bulbucan Claudiu34ORCID,Kirkpatrick Kyle5ORCID,Muntwiler Matthias2ORCID,Dreiser Jan2ORCID,Greber Thomas26ORCID,Avdoshenko Stas M.1ORCID,Dorn Harry5ORCID,Popov Alexey A.1ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstraße 20, 01069 Dresden, Germany

2. Swiss Light Source, Paul Scherrer Institute, CH-5232 Villigen PSI, Switzerland

3. The Division of Synchrotron Radiation Research, Lund University, SE-22100 Lund, Sweden

4. NanoLund, Lund University, Box 118, 22100 Lund, Sweden

5. Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061, USA

6. Physik-Institut der Universität Zürich, Winterthurerstr. 190, CH-8057 Zürich, Switzerland

Abstract

Whereas bulk Tb2@C79N is a single-molecule magnet with broad hysteresis, its monolayers on different substrates show the prevalence of a non-magnetic ground state near zero magnetic field and a metamagnetic transition with the field increase.

Funder

Vetenskapsrådet

H2020 Marie Skłodowska-Curie Actions

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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