RhCl(PPh3)3-mediated C–H oxyfunctionalization of pyrrolido-functionalized bisazoaromatic pincers: a combined experimental and theoretical scrutiny of redox-active and spectroscopic properties-Reference-Cited by-同舟云学术

RhCl(PPh3)3-mediated C–H oxyfunctionalization of pyrrolido-functionalized bisazoaromatic pincers: a combined experimental and theoretical scrutiny of redox-active and spectroscopic properties

Published:2016 Issue:13 Volume:45 Page:5720-5729
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghorui Tapas¹²³⁴⁵,Roy Sima¹²³⁴⁵,Pramanik Shuvam¹²³⁴⁵,Pramanik Kausikisankar¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Inorganic Chemistry Section

3. Jadavpur University

4. Kolkata – 700032

5. India

Abstract

Non-trivial coordination mode of symmetrical NNN ligands with Rh(iii) leads to redox-active NNO-scaffolds via C(sp²)–H oxyfunctionalization at rt, opening an opportunity to juxtapose different redox-active domains.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT05044H

Reference103 articles.

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3. Ambivalent binding between a radical-based pincer ligand and iron

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5. Comparison of the Electronic Properties of Diarylamido-Based PNZ Pincer Ligands: Redox Activity at the Ligand and Donor Ability Toward the Metal

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