Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources-Reference-Cited by-同舟云学术

Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources

Published:2016 Issue:14 Volume:45 Page:6234-6240
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Orr Samantha A.¹²³⁴⁵,Kennedy Alan R.¹²³⁴⁵,Liggat John J.¹²³⁴⁵,McLellan Ross¹²³⁴⁵,Mulvey Robert E.¹²³⁴⁵,Robertson Stuart D.¹²³⁴⁵

Affiliation:

1. WestCHEM

2. Department of Pure and Applied Chemistry

3. University of Strathclyde

4. Glasgow

5. UK

Abstract

Transmetallation of lithiodihydropyridines with Group 1 alkoxides provides facile access to reactive MH (M = Na, K) sources, which show significant structural diversity due in part to the distinct ways that Na/K engage with the σ (green) and π (red) donor systems of the DHP ligands.

Funder

Royal Society of Edinburgh

Engineering and Physical Sciences Research Council

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04224K

Reference73 articles.

1. XIV.—On the Constitution and Properties of Picoline, a new Organic Base from Coal-Tar