Structural and spectroscopic investigations of nine-coordinate redox active lanthanide complexes with a pincer O,N,O ligand-Reference-Cited by-同舟云学术

Structural and spectroscopic investigations of nine-coordinate redox active lanthanide complexes with a pincer O,N,O ligand

Published:2020 Issue:24 Volume:49 Page:8238-8246
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mouchel Dit Leguerrier D.¹²³⁴⁵,Barré R.¹²³⁴⁵,Bryden M.¹²³⁴⁵,Imbert D.¹⁶²⁷⁴^ORCID,Philouze C.¹²³⁴⁵,Jarjayes O.¹²³⁴⁵,Luneau D.⁸⁹⁵^ORCID,Molloy J. K.¹²³⁴⁵^ORCID,Thomas F.¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Grenoble Alpes

2. CNRS

3. DCM

4. 38000 Grenoble

5. France

6. CEA

7. IRIG-LCBM

8. LMI

9. Université Claude Bernard Lyon 1

Abstract

Three ligand molecules coordinate under their anionic diamagnetic form; the complexes (Gd, Eu, Yb, Lu) can undergo reversible oxidations, affording radical species, as demonstrated by spectro-electrochemistry.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01388A

Reference76 articles.

1. Radical Ligands Confer Nobility on Base-Metal Catalysts

2. Redox-active ligands in catalysis

3. New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands