Improving the quantum yield of luminescence for three-coordinated gold(<scp>i</scp>) TADF emitters by exploiting inversion symmetry and using perhaloaryl ligands-Reference-Cited by-同舟云学术

Improving the quantum yield of luminescence for three-coordinated gold(i) TADF emitters by exploiting inversion symmetry and using perhaloaryl ligands

Published:2024 Issue:34 Volume:12 Page:13255-13267
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Soldevilla Inés¹,El-Hachimi Abdel Ghafour¹^ORCID,Ramazanov Ruslan²,Valiev Rashid R.²,Olmos M. Elena¹^ORCID,Monge Miguel¹^ORCID,Sundholm Dage²^ORCID,Rodríguez-Castillo María¹^ORCID,López-de-Luzuriaga José M.¹^ORCID

Affiliation:

1. Departamento de Química, Universidad de La Rioja, Instituto de Investigación en Química de la Universidad de La Rioja (IQUR), Complejo Científico-Tecnológico, 26006 Logroño, Spain

2. Department of Chemistry, Faculty of Science, University of Helsinki, P.O. Box 55, (A.I: Virtasen aukio 1), FIN-00014, Finland

Abstract

New perhalophenyl gold(i)–tetraphosphino complexes are designed as highly efficient luminescent molecules. The electronegativity of the aryl groups and the symmetry of the molecules enable the formation of species with improved quantum yields at RT.

Funder

Research Council of Finland

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TC/D4TC02133A

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