Ruthenium catalysts bearing a benzimidazolylidene ligand for the metathetical ring-closure of tetrasubstituted cycloolefins

Author:

Borguet Yannick12345,Zaragoza Guillermo678910,Demonceau Albert12345,Delaude Lionel12345

Affiliation:

1. Laboratory of Organometallic Chemistry and Homogeneous Catalysis

2. Institut de Chimie (B6a)

3. Université de Liège

4. Sart-Tilman par 4000

5. Belgium

6. Unidade de Difracción de Raios X

7. Edificio CACTUS

8. Universidade de Santiago de Compostela

9. 15782 Santiago de Compostela

10. Spain

Abstract

Second-generation ruthenium–alkylidene complexes featuring the 1,3-di(2-tolyl)benzimidazol-2-ylidene ligand (BTol) are highly efficient catalysts for the synthesis of tetrasubstituted cycloolefins via ring-closing metathesis (RCM).

Funder

Fonds De La Recherche Scientifique - FNRS

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference139 articles.

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2. Green Metathesis Chemistry, NATO Science for Peace and Security Series-A: Chemistry and Biology, ed. V. Dragutan, A. Demonceau, I. Dragutan and E. S. Finkelshtein, Springer, Dordrecht, 2010

3. Metathesis in Natural Product Synthesis: Strategies, Substrates and Catalysts, ed. J. Cossy, S. Arseniyadis and C. Meyer, Wiley-VCH, Weinheim, 2010

4. Olefin Metathesis: Theory and Practice, ed. K. Grela, John Wiley & Sons, Hoboken, NJ, 2014

5. Olefin Metathesis and Beyond

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