New Pd(ii) complexes of sulfur ylides; synthesis, X-ray characterization, a theoretical study and catalytic activity toward the Mizoroki

New Pd(ii) complexes of sulfur ylides; synthesis, X-ray characterization, a theoretical study and catalytic activity toward the Mizoroki–Heck reaction

Published:2016 Issue:34 Volume:6 Page:28308-28315
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Sabounchei S. J.¹²³⁴,Ahmadianpoor M.¹²³⁴,Yousefi A.¹²³⁴,Hashemi A.¹²³⁴,Bayat M.¹²³⁴,Sedghi A.¹²³⁴,Akhlaghi Bagherjeri F.⁵⁶⁷,Gable R. W.⁵⁶⁷

Affiliation:

1. Faculty of Chemistry

2. Bu-Ali Sina University

3. Hamedan

4. Iran

5. School of Chemistry

6. University of Melbourne

7. Australia

Abstract

The reaction of sulfur ylides SMe₂C(H)C(O)R (R = 4-nitrophenyl, phenyl, and 3-nitrophenyl) with [PdCl₂(cod)] gives the new Pd(ii) complexes of type cis- and trans-[PdCl₂(SMe₂C(H)C(O)R)₂] (R = phenyl (1), 3-nitrophenyl (2), and 4-nitrophenyl (3)).

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA01390B

Reference49 articles.

1. Functionalized ylides: new trends in organometallic chemistry

2. Transition-metal-substituted diphosphenes. 12. Transition-metal sulfur ylide complexes. 25. Alkylidene transfer to the P:P double bond of diphosphenyl complexes by means of the sulfur ylides (CH3)2S(O):CH2 and (c-C3H4)SPh2. X-ray structure analysis of [cyclic] (.eta.5-C5Me5)(CO)2FePC(CH2CH2)PAr (Ar = 2,4,6-tert-Bu3C6H2)

3. Preparation of sulfur ylide complexes of platinum by phase transfer catalysis

4. Mixed sulphur and phosphorus ylide complexes of palladium formed by phase-transfer catalysis. X-Ray crystal structure of [Pd{(CH2)2S(O)Me}{Ph2PCH2PPh2CHC(O)Ph}]I·CH2Cl2·H2O

5. Preparation of sulfur ylide complexes of palladium by phase-transfer catalysis

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