Experimental and mechanistic insights into copper(ii)–dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivatives-Reference-Cited by-同舟云学术

Experimental and mechanistic insights into copper(ii)–dioxygen catalyzed oxidative N-dealkylation of N-(2-pyridylmethyl)phenylamine and its derivatives

Published:2017 Issue:43 Volume:15 Page:9164-9168
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wang Yang¹²³⁴⁵,Liu Haixiong¹²³⁴⁵,Zhang Xiaofeng¹²³⁴⁵,Zhang Zilong¹²³⁴⁵,Huang Deguang¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry

2. Fujian Institute of Research on the Structure of Matter

3. Chinese Academy of Sciences

4. Fuzhou

5. China

Abstract

An efficient Cu(ii)/O₂ catalytic system was experimentally explored for the N-dealkylation of PyCH₂NHPh and its derivatives via C–H bond activation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB02192E

Reference35 articles.

1. Structure and Spectroscopy of Copper−Dioxygen Complexes

2. Reactivity of Dioxygen−Copper Systems

3. Mononuclear Cu–O2 Complexes: Geometries, Spectroscopic Properties, Electronic Structures, and Reactivity

4. Monooxygenase Activity of Type 3 Copper Proteins

5. Hydrogen Atom Abstraction from Hydrocarbons by a Copper(III)-Hydroxide Complex

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