Cooperative reaction chemistry derived from a borata-diene framework-Reference-Cited by-同舟云学术

Cooperative reaction chemistry derived from a borata-diene framework

Published:2016 Issue:7 Volume:52 Page:1393-1396
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yu Jiangang¹²³,Kehr Gerald¹²³,Daniliuc Constantin G.¹²³,Erker Gerhard¹²³

Affiliation:

1. Organisch-Chemisches Institut der Universität Münster

2. 48149 Münster

3. Germany

Abstract

A bifunctional frustrated BH⁻/B hydridoborate nucleophile/borane Lewis acid pair is prepared starting from a zwitterionic phoshonium borata-diene by a sequence of sequential protonation/hydride attachment, followed by hydroboration with Piers' borane [HB(C₆F₅)₂]. The bifunctional product reduced carbon monoxide.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC07954C

Reference41 articles.

1. Establishing the Hydride Donor Abilities of Main Group Hydrides

2. Frustrated Lewis Pair Mediated Hydrogenations

3. Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates

4. α-CH acidity of alkyl–B(C6F5)2 compounds – the role of stabilized borata-alkene formation in frustrated Lewis pair chemistry

5. A Facile, One-Pot Synthesis of β-Substituted (Z)-Acrylonitriles Utilizing an α-Diaminoboryl Carbanion

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