Dimerization of confined Brønsted acids in enantioselective organocatalytic reactions-Reference-Cited by-同舟云学术

Dimerization of confined Brønsted acids in enantioselective organocatalytic reactions

Published:2023 Issue:38 Volume:14 Page:10580-10590
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Harden Ingolf¹^ORCID,Neese Frank¹,Bistoni Giovanni²^ORCID

Affiliation:

1. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm Platz 1, 45470 Mülheim an der Ruhr, Germany

2. Department of Chemistry, Biology and Biotechnology, University of Perugia, Via Elce di Sotto, 8, 06123 Perugia, Italy

Abstract

We shed light on the influence of the catalyst structure and reaction conditions on the spontaneity of the dimerization process for popular chiral organocatalysts derived from phosphoric acids using high-level quantum mechanical calculations.

Funder

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03769J

Reference85 articles.

1. Asymmetric Brønsted acid catalysis with chiral carboxylic acids

2. Synthesis of TRIP and Analysis of Phosphate Salt Impurities

3. A Powerful Brønsted Acid Catalyst for the Organocatalytic Asymmetric Transfer Hydrogenation of Imines

4. Chiral Brønsted Acid-Catalyzed Direct Mannich Reactions via Electrophilic Activation

5. Enantioselective Mannich-Type Reaction Catalyzed by a Chiral Brønsted Acid

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