Speciation and the structure of lead(ii) in hyper-alkaline aqueous solution

Author:

Bajnóczi Éva G.12345,Pálinkó István62345,Körtvélyesi Tamás723,Bálint Szabolcs891011,Bakó Imre891011,Sipos Pál12345,Persson Ingmar121314

Affiliation:

1. Department of Inorganic and Analytical Chemistry

2. University of Szeged

3. Szeged, Hungary

4. Materials and Solution Structure Research Group

5. Institute of Chemistry

6. Department of Organic Chemistry

7. Department of Physical Chemistry and Materials Science

8. Institute of Molecular Pharmacology

9. Research Centre for Natural Sciences

10. Hungarian Academy of Sciences

11. H-1025 Budapest, Hungary

12. Department of Chemistry and Biotechnology

13. Swedish University of Agricultural Sciences

14. Uppsala, Sweden

Abstract

In hyper-alkaline aqueous solutions, lead(ii) is present exclusively as [Pb(OH)3]. Other species, like [Pb(OH)4]2−, [PbOOH]or [PbO2]2−are not detectable.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference29 articles.

1. J. J. Brean and C. R.Stroup , Lead Poisoning: Exposure, Abatement, Regulation , CRC Press , USA , 1995

2. H. Casas and H.Sordo , Lead Chemistry, Analytical Aspects, Environmental Impacts and Health Effect , Elsevier , Amsterdam , 2006

3. M. I. Jeffrey , I. M.Ritchie and S. R.Labrooy , in Electrochemistry in Mineral and Metal Processing IV , ed. R. Woods , F. M. Doyle and P. E. Richardson , Electrochemistry Society , Pennington, NJ, USA , 1996 , p. 284

4. A. E. Martell and R. M.Smith , Critical Stability Constants , Plenum Press , London , 1975

5. C. F. Baes and R. E.Mesmer , The Hydrolysis of Cations , John Wiley & Sons , NewYork , 1976 , ch. 15.4

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