Syntheses and quadratic nonlinear optical properties of 2,7-fluorenylene- and 1,4-phenylene-functionalized o-carboranes-Reference-Cited by-同舟云学术

Syntheses and quadratic nonlinear optical properties of 2,7-fluorenylene- and 1,4-phenylene-functionalized o-carboranes

Published:2019 Issue:33 Volume:48 Page:12549-12559
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jiang Peng¹²³⁴,Wang Zhaojin¹²³⁴^ORCID,Moxey Graeme J.⁵⁶⁷⁸,Morshedi Mahbod⁵⁶⁷⁸,Barlow Adam⁵⁶⁷⁸,Wang Genmiao⁵⁶⁷⁸,Quintana Cristóbal⁵⁶⁷⁸,Zhang Chi¹²³⁴^ORCID,Cifuentes Marie P.¹²³⁴⁵,Humphrey Mark G.¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemical and Material Engineering

2. Jiangnan University

3. Wuxi 214122

4. China

5. Research School of Chemistry

6. Australian National University

7. Canberra

8. Australia

Abstract

Electron-withdrawing o-carboranes C-functionalized by one 2-donor-7-fluorenyl unit are shown to exhibit strong quadratic optical nonlinearities at 1064 nm; appending two donor-functionalized fluorenyl groups further enhances the NLO coefficients.

Funder

Project 211

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02645B