CPh3 as a functional group in P-heterocyclic chemistry: elimination of HCPh3 in the reaction of P-CPh3 substituted Li/Cl phosphinidenoid complexes with Ph2CO-Reference-Cited by-同舟云学术

CPh3 as a functional group in P-heterocyclic chemistry: elimination of HCPh3 in the reaction of P-CPh3 substituted Li/Cl phosphinidenoid complexes with Ph2CO

Published:2016 Issue:6 Volume:45 Page:2378-2385
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

García C. Murcia¹²³⁴,Ferao A. Espinosa⁵⁶⁷⁸⁹,Schnakenburg G.¹²³⁴,Streubel R.¹²³⁴

Affiliation:

1. Institut für Anorganische Chemie

2. Rheinische Friedrich-Wilhelms-Universität Bonn

3. D-53121 Bonn

4. Germany

5. Departamento de Química Orgánica

6. Facultad de Química

7. Universidad de Murcia

8. E-30071 Murcia

9. Spain

Abstract

Li/Cl phosphinidenoid complexes 2a–c react with benzaldehyde to give 3a–c, but with benzophenone formation of complexes 4 and 5 was observed, the latter revealing the elimination of HCPh₃.

Funder

Deutsche Forschungsgemeinschaft

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04595A

Reference51 articles.

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2. Organophosphorverbindungen mit terti�ren Alkylsubstituenten. V. Synthese und Reaktionen triphenylmethyl-substituierter Dihalogenphosphine TrtPX2 (Trt = Triphenylmethyl-, X = F, Cl, Br); Kristallstrukturen von Triphenylmethyldichlorphosphin TrtPCl2 und Triphenylmethylthiophosphons�uredifluorid TrtP(:S)F2