Different effects of metal-NHC bond cleavage on the Pd/NHC and Ni/NHC catalyzed α-arylation of ketones with aryl halides
Author:
Affiliation:
1. Platov South-Russian State Polytechnic University (NPI)
2. Russia
3. Zelinsky Institute of Organic Chemistry
4. Russian Academy of Sciences
5. Moscow
Abstract
Fundamental differences in the behavior of Pd/NHC and Ni/NHC catalytic systems in ketones α-arylation were elucidated and exploited.
Funder
Russian Science Foundation
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/QI/D0QI01411G
Reference100 articles.
1. Palladium-catalyzed α-arylation of carbonyls in the de novo synthesis of aromatic heterocycles
2. Palladium-Catalyzed α-Arylation Reactions in Total Synthesis
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4. Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles
5. Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization
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