Surface oxygen vacancies promoted Pt redispersion to single-atoms for enhanced photocatalytic hydrogen evolution

Author:

Cai Jinmeng12345,Cao Ang678,Wang Zhenbin678ORCID,Lu Siyu12345ORCID,Jiang Zheng910111213ORCID,Dong Xi-Yan12345ORCID,Li Xingang14151613ORCID,Zang Shuang-Quan12345ORCID

Affiliation:

1. Henan Key Laboratory of Crystalline Molecular Functional Materials

2. Green Catalysis Center

3. College of Chemistry

4. Zhengzhou University

5. Zhengzhou 450001

6. Technical University of Denmark

7. Lyngby DK 2800

8. Denmark

9. Shanghai Synchrotron Radiation Facility

10. Shanghai Institute of Applied Physics

11. Chinese Academy of Sciences

12. Shanghai 201800

13. P. R. China

14. School of Chemical Engineering & Technology

15. Tianjin University

16. Tianjin 300072

Abstract

In situ formed surface oxygen vacancies on TiO2 can redisperse Pt nanoparticles to stable single-atoms through hydrogen spillover effect. The catalyst displays both high photocatalytic hydrogen evolution performance and atom-utilization efficiency.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Zhengzhou University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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