Cyclic vs. acyclic alkyne towards Hg2+ ion detection: combined experimental and theoretical studies

Author:

Pal Adwitiya1,Goswami Bappaditya2,Thakur Arunabha1ORCID

Affiliation:

1. Department of Chemistry, Jadavpur University, Kolkata-700032, India

2. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur-741246, India

Abstract

Comparison between the alkynes in terminal and internally conjugated 1,3-diyne systems produces differences in molecular recognition, maintaining the HSAB principle.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference74 articles.

1. R. J.Ouellette and J. D.Rawn , 7 - Alkynes , Organic Chemistry , Academic Press , 2nd edn, 2018 , pp. 195–211

2. A. C.Hopkinson , The chemistry of the carbon-carbon triple bond , ed. S. Patai , John Wiley and Sons , Chichester , 1978 , p. 97

3. The Electrophilic Addition to Alkynes Revisited

4. Addition of alkynes and osmium carbynes towards functionalized dπ–pπ conjugated systems

5. The Nature of the Bonding in Transition-Metal Compounds

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