Stepwise assembly of heterometallic, heteroleptic “triblock Janus-type” metal–organic polyhedra

Author:

von Baeckmann Cornelia12,Ruiz-Relaño Sara12,Imaz Inhar12,Handke Marcel12,Juanhuix Judith3ORCID,Gándara Felipe4ORCID,Carné-Sanchez Arnau12ORCID,Maspoch Daniel125ORCID

Affiliation:

1. Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona 08193, Spain

2. Departament de Química, Facultat de Ciències Universitat Autònoma de Barcelona, Bellaterra 08193, Spain

3. Alba Synchrotron Light Facility, Cerdanyola del Vallès, Barcelona 08290, Spain

4. Materials Science Institute of Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), Calle Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain

5. ICREA, Pg. Lluís Companys 23, Barcelona 08010, Spain

Abstract

We present a novel strategy to assemble diverse metal ions and organic linkers into metal–organic polyhedra (MOPs). It involves use of a pre-assembled complex of a parent MOP to replicate this cage with a multicomponent character.

Funder

Agencia Estatal de Investigación

Agència de Gestió d'Ajuts Universitaris i de Recerca

Generalitat de Catalunya

Ministerio de Asuntos Económicos y Transformación Digital, Gobierno de España

“la Caixa” Foundation

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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