Metal triangles versus metal chains and terminal versus bridging hydrogen atoms in trinuclear osmium carbonyl hydride chemistry-Reference-Cited by-同舟云学术

Metal triangles versus metal chains and terminal versus bridging hydrogen atoms in trinuclear osmium carbonyl hydride chemistry

Published:2014 Issue:4 Volume:38 Page:1433-1440
ISSN:1144-0546
Container-title:New J. Chem.
language:en
Short-container-title:New J. Chem.

Author:

Xiang Mei¹²³⁴,Li Nan¹²³⁴,King R. Bruce⁵⁶⁷,Schaefer III Henry F.⁵⁶⁷

Affiliation:

1. State Key Laboratory of Explosion Science and Technology

2. School of Mechatronical Engineering

3. Beijing Institute of Technology

4. Beijing, P. R. China

5. Department of Chemistry and Center for Computational Chemistry

6. University of Georgia

7. Athens, USA

Abstract

Density functional theory studies on the H₂Os₃(CO)_n systems (n = 12, 11, 10, 9, 8) predict the experimentally observed species for n = 12, 11, and 10 with two terminal, one terminal and one bridging, and two bridging hydrogen atoms, respectively.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/NJ/C3NJ01479G

Reference29 articles.

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3. Preparation and characterization of members of a homologous series of dihydridocarbonyl compounds of osmium

4. Isolation of intermediates in metal carbonyl substitution: Adducts of H2Os3(CO)10

5. Solution structures and dynamics of complexes of decacarbonyldihydrotriosmium with Lewis bases

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