Synthesis and Lewis acidity of fluorophosphonium cations-Reference-Cited by-同舟云学术

Synthesis and Lewis acidity of fluorophosphonium cations

Published:2015 Issue:27 Volume:44 Page:12256-12264
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Caputo Christopher B.¹²³⁴,Winkelhaus Daniel¹²³⁴,Dobrovetsky Roman¹²³⁴,Hounjet Lindsay J.¹²³⁴,Stephan Douglas W.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada

Abstract

A series of fluorophosphonium salts, [R₃PF][X] (R = alkyl or aryl; X = FB(C₆F₅)₃, [B(C₆F₅)₄]), have been prepared by reactions of phosphine/borane frustrated Lewis pairs (FLPs) with XeF₂ or difluorophosphoranes with [Et₃Si][B(C₆F₅)₄].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00217F

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