Organo-palladium(ii) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions-Reference-Cited by-同舟云学术

Organo-palladium(ii) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions

Published:2015 Issue:16 Volume:44 Page:7230-7241
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wright Luka A.¹²³⁴,Hope Eric G.¹²³⁴,Solan Gregory A.¹²³⁴,Cross Warren B.¹²³⁴⁵,Singh Kuldip¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Leicester

3. Leicester LE1 7RH

4. UK

5. School of Science and Technology

Abstract

Oxidation of the palladium-phenyl N,N,N_mipp-pincer with Selectfluor leads to C–C coupling to give biphenyl; neither C–C nor C–F coupling is observed using the more sterically bulky N,N,N_dipp-pincer analogue.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00216H

Reference45 articles.

1. High-valent organometallic copper and palladium in catalysis

2. Structure and electronic properties of Pd(III) complexes

3. Palladium(III) in Synthesis and Catalysis

4. Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

5. Structural and reactivity comparison of analogous organometallic Pd(iii) and Pd(iv) complexes

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