Pursuing excitonic energy transfer with programmable DNA-based optical breadboards

Author:

Mathur Divita1ORCID,Díaz Sebastián A.2ORCID,Hildebrandt Niko34ORCID,Pensack Ryan D.5ORCID,Yurke Bernard5,Biaggne Austin5ORCID,Li Lan56,Melinger Joseph S.7ORCID,Ancona Mario G.78ORCID,Knowlton William B.5,Medintz Igor L.2ORCID

Affiliation:

1. Department of Chemistry, Case Western Reserve University, Cleveland OH 44106, USA

2. Center for Bio/Molecular Science and Engineering, Code 6900, USA

3. Department of Chemistry, Seoul National University, Seoul 08826, South Korea

4. Department of Engineering Physics, McMaster University, Hamilton, L8S 4L7, Canada

5. Micron School of Materials Science & Engineering, Boise State University, Boise, ID 83725, USA

6. Center for Advanced Energy Studies, Idaho Falls, ID 83401, USA

7. Electronics Science and Technology Division, Code 6800, U.S. Naval Research Laboratory, Washington, DC 20375, USA

8. Department of Electrical and Computer Engineering, Florida State University, Tallahassee, FL 32310, USA

Abstract

Nanoscale dye-based excitonic systems assembled on DNA origami in solution excited by a laser. Dyes engage in cascaded FRET with exciton movement guided by programmed elements engaging in homo- and hetero-energy transfer.

Funder

U.S. Department of Energy

Office of Naval Research

National Research Foundation of Korea

Seoul National University

U.S. Department of Defense

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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