In situ intramolecular catalytic 1,2-addition of allenoates to cyclic ketones towards polycyclic allenoates-Reference-Cited by-同舟云学术

In situ intramolecular catalytic 1,2-addition of allenoates to cyclic ketones towards polycyclic allenoates

Published:2015 Issue:7 Volume:13 Page:2153-2156
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Heinrich Clément F.¹²³⁴⁵,Miesch Michel¹²³⁴⁵,Miesch Laurence¹²³⁴⁵

Affiliation:

1. Université de Strasbourg

2. Institut de Chimie

3. UMR Unistra-CNRS 7177

4. Laboratoire de Chimie Organique Synthétique

5. 67008-Strasbourg

Abstract

Sequential deprotonation, isomerization of 3-alkynoates and subsequent 1,2-addition led to bicyclic allenoate in the presence of a catalytic amount of Cs₂CO₃.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02451F

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3. Science of Synthesis, ed. N. Krause, Thieme, Stuttgart, 2007, Vol. 44

4. Cascade Radical Cyclizations via Biradicals Generated from Enediynes, Enyne-Allenes, and Enyne-Ketenes

5. Palladium-Catalyzed Reactions of Allenes

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