A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes-Reference-Cited by-同舟云学术

A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes

Published:2016 Issue:87 Volume:6 Page:83547-83550
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

González-Calderón Davir¹²³⁴⁵,Morales-Reza Marco A.¹²³⁴⁵,Díaz-Torres Eduardo¹²³⁴⁵,Fuentes-Benítes Aydeé¹²³⁴⁵,González-Romero Carlos¹²³⁴⁵

Affiliation:

1. Departamento de Química Orgánica

2. Facultad de Química

3. Universidad Autónoma del Estado de México

4. Toluca

5. Mexico

Abstract

We report that the benzyl azido group is directly converted to carbonyls in good yields through a rapid hydrolysis (basic conditions) of benzylideneamides generated readily/efficiently in situ under a very simple procedure involving conventional reagents.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA13088G

Reference47 articles.

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3. Organic Azides: An Exploding Diversity of a Unique Class of Compounds

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5. Azide Chemistry - An Inorganic Perspective, Part I Metal Azides: Overview, General Trends and Recent Developments

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