Temperature-modulated diastereoselective transformations of 2-vinylindoles to tetrahydrocarbazoles and tetrahydrocycloheptadiindoles-Reference-Cited by-同舟云学术

Temperature-modulated diastereoselective transformations of 2-vinylindoles to tetrahydrocarbazoles and tetrahydrocycloheptadiindoles

Published:2018 Issue:16 Volume:16 Page:2910-2922
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Wani Imtiyaz Ahmad¹²³,Bhattacharyya Aditya¹²³,Sayyad Masthanvali¹²³,Ghorai Manas K.¹²³^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. India

Abstract

The Fe(OTf)₃-catalyzed dimerization of 2-vinylindolesviadiastereoselective [4 + 2] or [4 + 3] cyclization gives rise to tetrahydrocarbazoles at low temperature or tetrahydrocycloheptadiindoles at high temperature.

Funder

Indian Institute of Technology Kanpur

Department of Science and Technology, Ministry of Science and Technology

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB00228B

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