Cycloheptatrienyl trianion: an elusive bridge in the search of exchange coupled dinuclear organolanthanide single-molecule magnets
Author:
Affiliation:
1. Department of Chemistry and Biomolecular Sciences
2. University of Ottawa
3. Canada K1N 6N5
4. Theory of Nanomaterials Group
5. INPAC – Institute of Nanoscale Physics and Chemistry
6. Katholieke Universiteit Leuven
7. 3001 Leuven
8. Belgium
Abstract
Lanthanide inverse sandwich compounds of the cycloheptatrienyl trianion give rise to ferromagnetic exchange and slow relaxation of the magnetisation.
Funder
University of Ottawa
Canada Foundation for Innovation
Natural Sciences and Engineering Research Council of Canada
KU Leuven
Fonds Wetenschappelijk Onderzoek
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC01224H
Reference66 articles.
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3. Synthesis and crystal structure of [K(C12H24O6)][U(η-C7H7)2], the first cycloheptatrienyl sandwich compound
4. Inverse cycloheptatrienyl sandwich complexes. Crystal structure of [U(BH4)2(OC4H8)5][(BH4)3U(µ-η7,η7-C7H7)U(BH4)3]
5. Magnetic bistability in a metal-ion cluster
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