Highly selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over an amino-assisted Ru-based catalyst-Reference-Cited by-同舟云学术

Highly selective hydrogenation of dimethyl oxalate to methyl glycolate and ethylene glycol over an amino-assisted Ru-based catalyst

Published:2022 Issue:83 Volume:58 Page:11657-11660
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Song Lei¹,He Yan¹,Zhou Changan¹,Shu Guoqiang¹,Ma Kui¹^ORCID,Yue Hairong¹²^ORCID

Affiliation:

1. Multi-phases Reaction Engineering Laboratory, School of Chemical Engineering, Sichuan University, Chengdu 610065, China

2. Institute of New Energy and Low-Carbon Technology, Sichuan University, Chengdu 610207, China

Abstract

A Ru/NH2-MCM-41 catalyst was prepared via a coordination-assisted strategy for highly chemoselective hydrogenation of dimethyl oxalate to methyl glycolate (ca. 100%) and ethylene glycol (>90%) at low reaction temperature (343–433 K).

Funder

National Natural Science Foundation of China

Sichuan Province Science and Technology Support Program

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03346A

Reference25 articles.

1. Recent advances in the routes and catalysts for ethanol synthesis from syngas

2. Stable ethanol synthesis via dimethyl oxalate hydrogenation over the bifunctional rhenium-copper nanostructures: Influence of support

3. Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability

4. Surfactant-free nickel–silver core@shell nanoparticles in mesoporous SBA-15 for chemoselective hydrogenation of dimethyl oxalate

5. Ethylene glycol: properties, synthesis, and applications

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