On the role of the alkali cations on methanol thiolation
Author:
Affiliation:
1. Technische Universität München
2. Department of Chemistry and Catalysis Research Center
3. D-84747 Garching
4. Germany
5. Institute for Integrated Catalysis
Abstract
The electronegativity effect of the alkali cations on the formation of methanethiol by reaction of methanol and H2S was studied with K+, Rb+, and Cs+ supported on γ-Al2O3.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY01255A
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3. Promoting effect of SiO2 on the K2WO4/Al2O3 catalysts for methanethiol synthesis from methanol and H2S
4. G. A. Maw , in The chemistry of the sulphonium group, John Wiley & Sons, Ltd., 1981, pp. 703–770
5. Synthesis of methyl mercaptan from carbonyl sulfide over sulfide K2MoO4/SiO2
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