Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels

Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions

Published:2020 Issue:25 Volume:11 Page:6450-6456
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Reid Jolene P.¹²³⁴^ORCID,Hu Mingyou¹⁵⁶⁴,Ito Susumu¹⁵⁶⁴,Huang Banruo¹⁵⁶⁴,Hong Cynthia M.¹⁵⁶⁴,Xiang Hengye¹⁵⁶⁴,Sigman Matthew S.¹²³⁴,Toste F. Dean¹⁵⁶⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Utah

3. Salt Lake City

4. USA

5. University of California

6. Berkeley

Abstract

Chiral square planar gold(iii) complexes are employed as catalysts in asymmetric Diels–Alder reactions. The non-covalent interactions responsible for the enantioselectivity are revealed through multivariate linear regression analysis.

Funder

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

H2020 Marie Skłodowska-Curie Actions

National Science Foundation

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00497A

Reference43 articles.