Catalytic hydrogenation of liquid alkenes with a silica-grafted hydride pincer iridium(iii) complex: support for a heterogeneous mechanism-Reference-Cited by-同舟云学术

Catalytic hydrogenation of liquid alkenes with a silica-grafted hydride pincer iridium(iii) complex: support for a heterogeneous mechanism

Published:2015 Issue:9 Volume:5 Page:4575-4586
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Rimoldi M.¹²³,Fodor D.¹²³,van Bokhoven J. A.¹²³⁴⁵,Mezzetti A.¹²³

Affiliation:

1. Department of Chemistry and Applied Biosciences

2. ETH Zürich

3. Switzerland

4. Laboratory for Catalysis and Sustainable Chemistry

5. Paul Scherrer Institute

Abstract

The silica-grafted Ir(iii) hydride complex [IrH(O–SBA-15)(POCOP)], prepared by treating [IrH₂(O–SBA-15)] with SBA-15 (mesoporous silica), hydrogenates liquid alkenes at room temperature and under 1 atm H₂ without leaching into solution.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CY/C5CY00837A

Reference47 articles.

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3. Heterogeneous catalysis: Enigmas, illusions, challenges, realities, and emergent strategies of design

4. Single-Site Heterogeneous Catalysts

5. SOMC@PMS. Surface Organometallic Chemistry at Periodic Mesoporous Silica

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