Unexpected and divergent mechanosynthesis of furanoid-bridged fullerene dimers C120O and C120O2

Author:

Shao Gang1,Liu Yuan-Yuan1,Niu Chuang2ORCID,Yin Zheng-Chun2ORCID,Ye Shi-Qi1,Yao Yang-Rong3,Chen Muqing4ORCID,Chen Jun-Shen1,Xia Xu-Ling1,Yang Shangfeng3ORCID,Wang Guan-Wu125ORCID

Affiliation:

1. Hefei National Research Center for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China

2. Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, and School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, P. R. China

3. Hefei National Research Center for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, and Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, Anhui, 230026, P. R. China

4. School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, Guangdong, 523808, P. R. China

5. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu 730000, P. R. China

Abstract

Divergent mechanosynthesis of furanoid-bridged fullerene dimers C120O and C120O2 was achieved from the FeCl3-mediated reaction of C60 with H2O under different solvent-free ball-milling conditions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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