Pd-catalyzed enantioselective cyclopropanation of nitriles with mono substituted allyl carbonates enabled by the bulky N-heterocyclic carbene ligand-Reference-Cited by-同舟云学术

Pd-catalyzed enantioselective cyclopropanation of nitriles with mono substituted allyl carbonates enabled by the bulky N-heterocyclic carbene ligand

Published:2019 Issue:45 Volume:55 Page:6449-6452
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Gao-Peng¹²³⁴⁵,Huang Shuai¹²³⁴⁵,Jiang Yang-Jie¹²³⁴⁵,Liu Xiu-Yan¹²³⁴⁵,Ding Chang-Hua¹²³⁴⁵,Wei Yin¹²³⁴⁵^ORCID,Hou Xue-Long¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Center for Excellence in Molecular Synthesis

3. Shanghai Institute of Organic Chemistry

4. Chinese Academy of Sciences (SIOC)

5. China

Abstract

Enantioselective cyclopropanation of nitriles with allyl reagents was realized using Pd/NHC as a catalyst and the reasons for the cyclopropanation were investigated.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Science and Technology Commission of Shanghai Municipality

Croucher Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC01960J

Reference48 articles.

1. Synthesis of cyclopropane containing natural products

2. Cyclopropanation Strategies in Recent Total Syntheses

3. Stereoselective Cyclopropanation Reactions

4. Recent Advances in Asymmetric Catalytic Metal Carbene Transformations

5. Enantioselective Cyclopropanation of a Wide Variety of Olefins Catalyzed by Ru(II)–Pheox Complexes

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